Pool Chemicals: Complete Guide
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Pool Chemicals: Complete Guide

By Equipa ManutencaoPiscinas10 min read

Introduction

Keeping pool water clean and safe requires the use of various chemicals, each with a specific function. Understanding what each product does, when to use it and how to dose correctly is fundamental for effective and economical maintenance.

In Margem Sul, where we face specific challenges such as well water with high hardness, maritime influence and intense sun exposure, knowing the available pool chemicals well helps choose the most suitable solutions for each situation.

This complete guide presents all the essential pool chemicals, from disinfectants to special products, with clear instructions for use, dosages and safety precautions.

Product Categories

Overview

CategoryMain FunctionFrequency of Use
DisinfectantsKill microorganismsContinuous
pH regulatorsBalance acidityAs needed
Alkalinity regulatorsStabilise pHAs needed
AlgicidesPrevent/eliminate algaeWeekly/treatment
Flocculants/clarifiersImprove clarityAs needed
Special productsSpecific problemsOccasional

Disinfectants

Types of Chlorine

TypeFormCYABest For
Calcium hypochloriteGranules/tabletsNoShock treatments
Dichloroisocyanurate (dichlor)GranulesYesQuick chlorination
Trichloroisocyanurate (trichlor)TabletsYesContinuous chlorination
Sodium hypochloriteLiquidNoAutomatic dosing

Stabilised vs Unstabilised Chlorine

CharacteristicStabilisedUnstabilised
Contains CYAYesNo
UV protectionYesNo
AccumulationCan accumulate CYANo accumulation
Ideal useDaily maintenanceShocks, indoor pools
CostLower medium-termHigher (more consumption)

Chlorine Dosage

For maintenance (1-3 ppm):

Pool Volume200g TabletGranules/day
20 m³1 tablet/week20-40g
40 m³2 tablets/week40-80g
60 m³3 tablets/week60-120g
80 m³4 tablets/week80-160g

For shock (10+ ppm):

VolumeCalcium hypochlorite 65%
20 m³300-400g
40 m³600-800g
60 m³900-1200g
80 m³1200-1600g

💡 Dica Profissional

In Margem Sul, with intense sun during summer, unstabilised chlorine can lose 90% of its effectiveness in just a few hours. Always use stabilised chlorine for daily maintenance, reserving unstabilised for shock treatments.

Bromine

Characteristics:

  • Effective at high temperatures
  • Less irritating than chlorine
  • Doesn't produce strong smell
  • More expensive than chlorine

Ideal for:

  • Spas and jacuzzis
  • Heated indoor pools
  • Users sensitive to chlorine

ParameterIdeal Value
Free bromine3-5 ppm
pH7.2-7.8

Active Oxygen (Hydrogen Peroxide)

Characteristics:

  • Chlorine-free
  • No smell
  • Gentle on skin and eyes
  • Requires more maintenance

Dosage:

  • Maintenance: 50-100 ml/m³ per week
  • Shock: 200-300 ml/m³

pH Regulators

pH Minus (Reducer)

Typical composition:

  • Sodium bisulphate (solid)
  • Hydrochloric acid (liquid)
  • Sulphuric acid (liquid)

When to use:

  • pH above 7.6

Approximate dosage (pH from 7.8 to 7.4):

VolumeSodium bisulphateHydrochloric acid 33%
20 m³200-300g150-200 ml
40 m³400-600g300-400 ml
60 m³600-900g450-600 ml
80 m³800-1200g600-800 ml

pH Plus (Increaser)

Typical composition:

  • Sodium carbonate (soda ash)

When to use:

  • pH below 7.2

Approximate dosage (pH from 7.0 to 7.4):

VolumeSodium carbonate
20 m³150-200g
40 m³300-400g
60 m³450-600g
80 m³600-800g

💡 Dica Profissional

Never add more than 300g of pH regulator per 10 m³ at once. Wait at least 4 hours with filtration running before testing again and making further adjustments.

Alkalinity Regulators

Alkalinity Increaser

Composition:

  • Sodium bicarbonate

When to use:

  • Alkalinity below 80 ppm
  • Unstable pH (rises and falls easily)

Dosage (to increase 10 ppm):

VolumeSodium bicarbonate
20 m³300g
40 m³600g
60 m³900g
80 m³1200g

Alkalinity Reducer

Method:

  • Use hydrochloric acid or sodium bisulphate
  • Add in small doses over several days
  • Reducing pH also reduces alkalinity

Stabiliser (Cyanuric Acid)

Function

Protects chlorine from UV degradation, extending its effectiveness.

Dosage

To achieve 30-40 ppm:

VolumeCyanuric acid
20 m³600-800g
40 m³1200-1600g
60 m³1800-2400g
80 m³2400-3200g

Precautions

CYA LevelSituationAction
0-20 ppmVery lowAdd stabiliser
30-50 ppmIdealMaintain
50-80 ppmHighDon't add more
> 80 ppmProblematicDilute water
> 100 ppmChlorine lockPartial draining

💡 Dica Profissional

Stabiliser doesn't degrade and only leaves the pool with the water. In pools that have used stabilised chlorine for years, CYA can accumulate excessively. In Margem Sul, we recommend renewing 20-30% of the water annually.

Algicides

Types of Algicides

TypeActionConcentrationUse
Quaternary (quat)Preventive5-10%Weekly maintenance
Polymeric (polyquat)Preventive30-60%Maintenance, no foam
CopperCurativeVariableAlgae treatment
Copper sulphateCurative100%Black algae

Dosage

Weekly maintenance:

VolumeQuaternary algicidePolymeric algicide
20 m³100-200 ml50-100 ml
40 m³200-400 ml100-200 ml
60 m³300-600 ml150-300 ml
80 m³400-800 ml200-400 ml

Curative treatment (visible algae):

  • Triple the maintenance dose
  • Combine with shock treatment

Precautions with Copper Algicides

AspectCaution
pHMaintain 7.2-7.6 (prevents precipitation)
StainsMay stain light finishes
DosageDon't exceed recommendation
HairMay tint light hair green

Flocculants and Clarifiers

Difference

CharacteristicFlocculantClarifier
MechanismClumps large particlesClumps small particles
ResultSettles to bottomImproves filtration
After useVacuum residueClean filter
SpeedFast (6-12h)Gradual (24-48h)

Flocculant

When to use:

  • Very cloudy water
  • After algae treatment
  • Fine particles in suspension

Procedure:

  1. Adjust pH to 7.2-7.6
  2. Turn off pump
  3. Add diluted flocculant
  4. Wait 8-12 hours
  5. Vacuum to waste (not to filter)
  6. Turn on filtration

Dosage:

VolumeLiquid flocculant
20 m³200-400 ml
40 m³400-800 ml
60 m³600-1200 ml
80 m³800-1600 ml

Clarifier

When to use:

  • Slightly cloudy water
  • Preventive maintenance
  • Improve filter efficiency

Weekly dosage:

VolumeClarifier
20 m³50-100 ml
40 m³100-200 ml
60 m³150-300 ml
80 m³200-400 ml

Calcium Hardness Regulator

Calcium Increaser

Composition:

  • Calcium chloride

When to use:

  • Hardness below 200 ppm
  • Liner or vinyl finish

Dosage (to increase 10 ppm):

VolumeCalcium chloride
20 m³200g
40 m³400g
60 m³600g
80 m³800g

Anti-Scale (Sequestrant)

When to use:

  • Hardness above 400 ppm
  • Well water
  • Scale deposits

Dosage:

UseQuantity
Initial500 ml/50 m³
Weekly maintenance100 ml/50 m³

💡 Dica Profissional

In Margem Sul, especially in Palmela, Moita and Azeitão, well water frequently has hardness above 400 ppm. Preventive use of anti-scale is essential to avoid deposits on equipment and surfaces.

Special Products

Metal Sequestrant

Function:

  • Prevents iron and copper stains
  • Keeps metals in solution

When to use:

  • Well water
  • After metal stains
  • Preventively

Dosage:

  • Initial: 500 ml/50 m³
  • Maintenance: 100 ml/50 m³ fortnightly

Stain Remover

Stain TypeProductDosage
Organic (leaves)Chlorine + brushingShock + brush
Metallic (iron)Ascorbic acid100g/10 m³
ScaleHydrochloric acidLocalised application
Black algaeCopper sulphate + chlorineCombined treatment

Tile Cleaner (Descaler)

Function:

  • Removes deposits at waterline
  • Eliminates oils and grease

Use:

  1. Apply with sponge
  2. Scrub gently
  3. Rinse well
  4. Frequency: fortnightly

Antifoam

When to use:

  • Persistent foam on surface
  • After excessive quaternary algicide use
  • Cleaning products in water

Dosage:

  • 50-100 ml per 50 m³

Storage and Safety

Storage Rules

RuleReason
Cool, dry placePrevents degradation
Away from sunSome products degrade
Separate oxidisers from acidsAvoids dangerous reactions
Original containersIdentification and safety
Out of children's reachSafety
Ventilated areaPrevents vapour buildup

Incompatibilities

NEVER MixResult
Chlorine + acidChlorine gas (toxic)
Chlorine + ammoniaChloramines (toxic)
Different oxidisersViolent reaction
Concentrated acid + baseExothermic reaction

Protective Equipment

ProductMinimum PPE
Chlorine granules/tabletsGloves, goggles
AcidsGloves, goggles, apron
Liquid productsGloves
AllDon't inhale vapours

How to Add Products

General Rules

  1. Always dilute solid products in bucket with water before adding
  2. Add around the perimeter, not at one point
  3. With filtration running (except flocculant)
  4. Wait between different products (minimum 30 minutes)
  5. Don't swim for 30-60 minutes after adding

Order of Addition

If you need to add several products:

  1. Adjust alkalinity (wait 4h)
  2. Adjust pH (wait 4h)
  3. Add stabiliser if needed (wait 24h)
  4. Add chlorine or disinfectant
  5. Algicide (after chlorine normalises)
  6. Clarifier (last)

Dosage Calculations

Basic Formula

Quantity = (Pool volume × Dosage per m³) / Product concentration

Practical Example

Problem: Raise chlorine from 0.5 ppm to 2 ppm in a 50 m³ pool Increase needed: 1.5 ppm Product: Dichlor 56%

Quantity = (50 m³ × 1.5g) / 0.56 = 134g of dichlor

Quick Conversion Table

To increase56% granular chlorine per 10 m³
1 ppm18g
2 ppm36g
5 ppm (shock)90g
10 ppm (strong shock)180g

Frequently Asked Questions

Can I mix products from different brands?

Yes, as long as they are the same type (e.g., two quaternary algicides). Never mix different categories in the same container. Add each product separately to the pool.

What's the shelf life of pool chemicals?

Most maintain effectiveness for 2-3 years if stored correctly. Granular chlorine may lose potency after 1 year opened. Always check packaging for specific dates.

Why does chlorine disappear so quickly?

Common causes: lack of stabiliser (CYA), excess organic matter, high temperature, intense sun, or incorrect pH. In Margem Sul, strong summer sun is often the culprit if CYA is low.

Is it better to use tablets or granular chlorine?

Tablets are more convenient for continuous chlorination (in floater or skimmer). Granules are better for quick adjustments and shock treatments. Most owners use both.

How long should I wait to swim after adding chemicals?

Depends on the product. General rule: 30-60 minutes for normal adjustments. After shock, wait until chlorine drops below 3 ppm (test before swimming).

Conclusion

Correct use of pool chemicals is essential for keeping water clean, safe and pleasant. The main points are:

  • Know each product and its specific function
  • Follow recommended dosages - more is not better
  • Respect the order of addition when using multiple products
  • Store correctly and never mix incompatible products
  • Use protection when handling chemicals
  • Test regularly to confirm results

In Margem Sul, with the particularities of local water, it's especially important to use anti-scale and metal sequestrant preventively, in addition to maintaining adequate stabiliser levels.

If you need professional help with the chemical treatment of your pool in Margem Sul, ManutençãoPiscinas is here to help. Contact us for a no-obligation quote.

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